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SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE/ PREPARATION OF THE COMPANY/ UNDERTAKING Product Name: Application: Company: Address: Telephone: Fax:
NITOPROOF 10 (formerly known as Mulseal HD) Waterproofing Coating/ Membrane Fosroc Sdn. Bhd. 8, Jalan Trompet 33/8, Section 33, 40400 Shah Alam, Selangor, Malaysia 03-51915660 03-51916960
2. COMPOSITION/ INFORMATION ON INGREDIENTS Composition:
Bitumen, Water, Synthetic Rubber, Potassium Hydroxide, Fungicide.
Hazardous Ingredient(s)
Symbol
Risk Phrases
Other Information
%
Bitumen
Xi
R36/37/38
Cas No.: 64742-93-4
>50
This product contains ingredients classified as Hazardous. However, they are NOT present in sufficient quantities of warrant classifying the product as Hazardous. All constituents of this product are listed in EINECS (European Inventory of Existing Commercial Chemical Substances) or ELINCS (European List of New Chemical Substances) or are exempt. Refer to Section 8 for Occupational Exposure Limits.
3. HAZARDS IDENTIFICATION Irritant.
Irritant
4. FIRST AID MEASURES Eyes: Issue No: 03
Irrigate immediately with copious of quantities of water for
Date: 01/06/2007
Product Name: Nitoproof 10
Page 1 of 5
several minutes. Obtain medical attention if irritant persist.
Skin:
Wash immediately with soap and water or suitable skin cleanser. Obtain medical advice if skin disorders develop.
Inhalation: Ingestion:
Remove from exposure – unlikely to occur. Do NOT induce vomiting. Obtain medical attention urgently. Wash out mouth with water.
5. FIRE FIGHTING MEASURES Suitable Extinguishing Media: Special Exposure Hazards: Special Protective Equipment:
None. Not flammable. None. None.
6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Environmental Precautions: Decontamination Procedures:
Wear protective clothing, gloves and eye/face protection. Prevent entry into drain, sewers and watercourses. Soak up with inert absorbent or contain and remove by best available means. Dispose of as waste.
7. HANDLING AND STORAGE Handling: Storage:
Avoid skin and eye . Store in cool, dry area. Protect from frost.
8. EXPOSURE CONTROL/ PERSONAL PROTECTION Occupational Exposure Limits: Engineering Control Measures: Personal Protective Equipment:
None Assigned
No specific ventilation requirement noted. Avoid skin and eye . Wear impervious gloves (e.g. PVC), in case of repeated or prolonged .
9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour pH (concentrate)
Issue No: 03
Date: 01/06/2007
Liquid Black Typical 9.0 – 11.0
Product Name: Nitoproof 10
Page 2 of 5
Boiling Point / Range (°C) Flash Point (closed °C ) Vapour Pressure (kPa at 20 °C) Relative Density (at 20 °C) Water Solubility
100 None 2.3 (water) 1.05 Emulsifiable
10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to Avoid: Hazardous Decomposition Products:
Stable. Temperature (°C) below 2 and above 80. Strong acids. Thermal decomposition: - Sulphur compounds including hydrogen sulphide.
11. TOXICOLOGICAL INFORMATION The following toxicological assessment is based on knowledge of the toxicity of the product’s components. Oral LD50, rat > 2gm/kg.
Health Effects On eyes: On skin: By Inhalation: By Ingestion: Chronic:
Irritation. Unlikely to irritate on brief or occasional exposure. Low volatility makes inhalation unlikely at ambient temperatures. Low order of acute toxicity. May cause irritation of mouth, throat and digestive tract. Repeated and prolonged , may lead to skin disorders.
12. ECOLOGICAL INFORMATION Environmental Assessment:
When used and disposed of as intended, no adverse environmental effects are foreseen.
Mobility: Persistence & Degradability: Bioaccumulated Potential: Ecotoxicity:
Mobile liquid. Emulsifiable in water. Not readily biodegrable. Not expected to be bioaccumulative. Expected to be ecotoxic to fish/daphnia/algae.
13. DISPOSAL CONSIDERATIONS
Issue No: 03
Date: 01/06/2007
Product Name: Nitoproof 10
Page 3 of 5
Disposal must be in accordance with local and national legislation.
Unused Product: Used / Contaminated Product: Packaging:
Disposed of through an authorized waste contractor to a license site. Do not empty into drains, sewers or watercourses. As for unused product. May be steam cleaned and recycled.
14. TRANSPORT INFORMATION This product is NOT classified as dangerous for transport
UN number: Class: IMO: Class: IATA/ICAO: Class: ADR: Transport Name: Hazchem/Kemler Code:
Packing Group:
Marine pollutant:
Packing Group:
Item:
15. REGULATORY INFORMATION Hazard Label Data: Named Ingredients: UN Number: Symbol(s): Risk Phrases: Safety Phrases:
None None Xi R36/37/38
Irritating to eyes, respiratory system and skin.
S24/25 S26
Avoid with skin and eyes. In case of with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye / face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Substances Directive, 67/548/EEC and
S36/37/39 S45
EC Directives:
Statutory Instruments:
Issue No: 03
Date: 01/06/2007
Dangerous adaptations. Dangerous Preparations, 88/379/EEC. Safety Data Sheet directive, 91/155/EEC. Chemicals (Hazard Information and Packaging) Regs. 1993 (SI 1092). Control of Substances Hazardous to Health Regs. 1994 (SI 3246). Environmental Protection Act 1990.
Product Name: Nitoproof 10
Page 4 of 5
Codes Practice: Guidance Note:
Waste Management. The Duty of Care.
The above information is available from HMSO.
16. OTHER INFORMATION The data and advice given apply when the product is used for the stated application or applications. The product is not sold as suitable for any other application. Use of the product for applications other than as stated in this sheet may give rise to risks not mentioned in this sheet. The product should not be used other than for the stated application or applications without seeking advice from FOSROC Sdn Bhd. If this product has been purchased to a third party for use at work, it is the purchaser’s duty to take all necessary steps to secure that any person handling or using the product is provided with the information in this sheet. It is the responsibility and duty of the employer to inform employees and others who may be affected of any hazards described to this sheet and of any precautions, which should be taken. This sheet does not constitute or substitute for the s own assessment of workplace risk, as required by other health and safety legislation. Further copies of this Safety Data Sheet may be obtained from FOSROC Sdn Bhd, Malaysia.
Date Printed: 01/06/2007
Issue No: 03
Date: 01/06/2007
SDS Reference: Nitoproof 10 (formerly known as Mulseal HD)
Product Name: Nitoproof 10
Page 5 of 5
NITOPROOF 10 (formerly known as Mulseal HD) Waterproofing Coating/ Membrane Fosroc Sdn. Bhd. 8, Jalan Trompet 33/8, Section 33, 40400 Shah Alam, Selangor, Malaysia 03-51915660 03-51916960
2. COMPOSITION/ INFORMATION ON INGREDIENTS Composition:
Bitumen, Water, Synthetic Rubber, Potassium Hydroxide, Fungicide.
Hazardous Ingredient(s)
Symbol
Risk Phrases
Other Information
%
Bitumen
Xi
R36/37/38
Cas No.: 64742-93-4
>50
This product contains ingredients classified as Hazardous. However, they are NOT present in sufficient quantities of warrant classifying the product as Hazardous. All constituents of this product are listed in EINECS (European Inventory of Existing Commercial Chemical Substances) or ELINCS (European List of New Chemical Substances) or are exempt. Refer to Section 8 for Occupational Exposure Limits.
3. HAZARDS IDENTIFICATION Irritant.
Irritant
4. FIRST AID MEASURES Eyes: Issue No: 03
Irrigate immediately with copious of quantities of water for
Date: 01/06/2007
Product Name: Nitoproof 10
Page 1 of 5
several minutes. Obtain medical attention if irritant persist.
Skin:
Wash immediately with soap and water or suitable skin cleanser. Obtain medical advice if skin disorders develop.
Inhalation: Ingestion:
Remove from exposure – unlikely to occur. Do NOT induce vomiting. Obtain medical attention urgently. Wash out mouth with water.
5. FIRE FIGHTING MEASURES Suitable Extinguishing Media: Special Exposure Hazards: Special Protective Equipment:
None. Not flammable. None. None.
6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Environmental Precautions: Decontamination Procedures:
Wear protective clothing, gloves and eye/face protection. Prevent entry into drain, sewers and watercourses. Soak up with inert absorbent or contain and remove by best available means. Dispose of as waste.
7. HANDLING AND STORAGE Handling: Storage:
Avoid skin and eye . Store in cool, dry area. Protect from frost.
8. EXPOSURE CONTROL/ PERSONAL PROTECTION Occupational Exposure Limits: Engineering Control Measures: Personal Protective Equipment:
None Assigned
No specific ventilation requirement noted. Avoid skin and eye . Wear impervious gloves (e.g. PVC), in case of repeated or prolonged .
9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour pH (concentrate)
Issue No: 03
Date: 01/06/2007
Liquid Black Typical 9.0 – 11.0
Product Name: Nitoproof 10
Page 2 of 5
Boiling Point / Range (°C) Flash Point (closed °C ) Vapour Pressure (kPa at 20 °C) Relative Density (at 20 °C) Water Solubility
100 None 2.3 (water) 1.05 Emulsifiable
10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to Avoid: Hazardous Decomposition Products:
Stable. Temperature (°C) below 2 and above 80. Strong acids. Thermal decomposition: - Sulphur compounds including hydrogen sulphide.
11. TOXICOLOGICAL INFORMATION The following toxicological assessment is based on knowledge of the toxicity of the product’s components. Oral LD50, rat > 2gm/kg.
Health Effects On eyes: On skin: By Inhalation: By Ingestion: Chronic:
Irritation. Unlikely to irritate on brief or occasional exposure. Low volatility makes inhalation unlikely at ambient temperatures. Low order of acute toxicity. May cause irritation of mouth, throat and digestive tract. Repeated and prolonged , may lead to skin disorders.
12. ECOLOGICAL INFORMATION Environmental Assessment:
When used and disposed of as intended, no adverse environmental effects are foreseen.
Mobility: Persistence & Degradability: Bioaccumulated Potential: Ecotoxicity:
Mobile liquid. Emulsifiable in water. Not readily biodegrable. Not expected to be bioaccumulative. Expected to be ecotoxic to fish/daphnia/algae.
13. DISPOSAL CONSIDERATIONS
Issue No: 03
Date: 01/06/2007
Product Name: Nitoproof 10
Page 3 of 5
Disposal must be in accordance with local and national legislation.
Unused Product: Used / Contaminated Product: Packaging:
Disposed of through an authorized waste contractor to a license site. Do not empty into drains, sewers or watercourses. As for unused product. May be steam cleaned and recycled.
14. TRANSPORT INFORMATION This product is NOT classified as dangerous for transport
UN number: Class: IMO: Class: IATA/ICAO: Class: ADR: Transport Name: Hazchem/Kemler Code:
Packing Group:
Marine pollutant:
Packing Group:
Item:
15. REGULATORY INFORMATION Hazard Label Data: Named Ingredients: UN Number: Symbol(s): Risk Phrases: Safety Phrases:
None None Xi R36/37/38
Irritating to eyes, respiratory system and skin.
S24/25 S26
Avoid with skin and eyes. In case of with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye / face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Substances Directive, 67/548/EEC and
S36/37/39 S45
EC Directives:
Statutory Instruments:
Issue No: 03
Date: 01/06/2007
Dangerous adaptations. Dangerous Preparations, 88/379/EEC. Safety Data Sheet directive, 91/155/EEC. Chemicals (Hazard Information and Packaging) Regs. 1993 (SI 1092). Control of Substances Hazardous to Health Regs. 1994 (SI 3246). Environmental Protection Act 1990.
Product Name: Nitoproof 10
Page 4 of 5
Codes Practice: Guidance Note:
Waste Management. The Duty of Care.
The above information is available from HMSO.
16. OTHER INFORMATION The data and advice given apply when the product is used for the stated application or applications. The product is not sold as suitable for any other application. Use of the product for applications other than as stated in this sheet may give rise to risks not mentioned in this sheet. The product should not be used other than for the stated application or applications without seeking advice from FOSROC Sdn Bhd. If this product has been purchased to a third party for use at work, it is the purchaser’s duty to take all necessary steps to secure that any person handling or using the product is provided with the information in this sheet. It is the responsibility and duty of the employer to inform employees and others who may be affected of any hazards described to this sheet and of any precautions, which should be taken. This sheet does not constitute or substitute for the s own assessment of workplace risk, as required by other health and safety legislation. Further copies of this Safety Data Sheet may be obtained from FOSROC Sdn Bhd, Malaysia.
Date Printed: 01/06/2007
Issue No: 03
Date: 01/06/2007
SDS Reference: Nitoproof 10 (formerly known as Mulseal HD)
Product Name: Nitoproof 10
Page 5 of 5
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