Msds Chesterton 274 49283d
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MATERIAL SAFETY DATA SHEET in accordance with 1907/2006/EC (REACH) 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product Name: Revision: MSDS No.
274 Industrial Degreaser (Aerosol)
5 August 2010
Date of issue:
6 July 2007
207A-14
Not classified as hazardous according to criteria of Safe Work Australia. Company: A.W. CHESTERTON COMPANY 860 Salem Street Groveland, MA 01834-1507, USA Tel.: +1 978-469-6446 Fax: +1 978-469-6785 (Mon. - Fri. 8:30 - 5:00 PM EST) E-mail (MSDS questions): [email protected] MSDS requests: www.chesterton.com
Supplier:
For Chemical Emergency: 24 hours per day, 7 days per week Call Infotrac: 1-800-535-5053 Outside N. America: +1 352-323-3500 (collect) Use:
Petroleum base cleaner. Dissolves grease, oil, tar and other similar water insoluble soils generally encountered in the industrial and marine environments.
2. HAZARDS IDENTIFICATION Highly flammable. Contents under pressure. Repeated exposure may cause skin dryness or cracking. As with any organic solvent based product, care should be taken to avoid excessive inhalation of vapors. This is especially important in enclosed areas or areas with poor ventilation. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Ingredients¹ % Wt. CAS No. Naphtha (Petroleum), Hydrotreated Heavy* 85-95 64742-48-9 Petroleum Gases, Liquefied, Sweetened** 10-20 68476-86-8
EC No. 265-150-3 270-705-8
Symbol Xn F+
R-phrases 65-66 12
See section 15 for text of risk phrases on the label and section 16 for others. *Contains less than 0.1 % w/w Benzene. **Contains less than 0.1 % w/w 1,3-Butadiene.
© A.W. Chesterton Company, 2010 All Rights Reserved. ® Reg. US Patent and TM Office
¹Classified according to:
* 29 CFR 1910.1200, 1915, 1916, 1917 * Mass. Right-to-Know Law (ch. 40, M.G.L..O. 111F) * California Proposition 65 * Controlled Products Regulations * 67/548/EEC, 1272/2008/EC (ATP01) 99/45/EC and 75/324/EEC * Worksafe Australia [NOHSC: 1008 (2004)]
Page 1 of 5
Product: 274 Industrial Degreaser (Aerosol) Date: 5 August 2010
MSDS No.: 207A-14
4. FIRST AID MEASURES Remove to fresh air. If not breathing, ister artificial respiration. physician immediately. Inhalation: Skin :
Wash skin with soap and water. physician if irritation persists.
Eye :
Flush eyes for at least 15 minutes with large amounts of water. physician if irritation persists.
Ingestion:
Do not induce vomiting. physician immediately.
Advice to Physician:
Treat symptoms.
5. FIRE-FIGHTING MEASURES Extinguishing Methods:
Carbon Dioxide, dry chemical, foam or water spray
Unusual Fire and Explosion Hazards:
Pressurized containers, when heated, are a potential explosive hazard.
Special Fire Fighting Measures:
Cool exposed containers with water. Recommend Firefighters wear self-contained breathing apparatus.
Flammability Classification:
NFPA: Storage Level III; 16CFR 1500.3 Extremely flammable aerosol
HAZCHEM Emergency Action Code: 2 Y 6. ACCIDENTAL RELEASE MEASURES Utilize exposure controls and personal protection as specified in Section 8. Personal Precautions: Environmental Precautions:
Keep out of sewers, streams and waterways.
Methods of Clean Up:
Evacuate area. Provide adequate ventilation. Contain spill to a small area. Keep away from sources of ignition - No smoking. If removal of ignition sources is not possible, then flush material away with water. Pick up with absorbent material (sand, sawdust, clay, etc.) and place in a suitable container for disposal. Refer to section 13 for disposal advice.
7. HANDLING AND STORAGE Handling: Shake well before using. Keep away from sources of ignition - No smoking. After handling, wash before eating, drinking or smoking. Vapors are heavier than air and will collect in low areas. Vapor accumulations could flash and/or explode if ignited. Utilize exposure controls and personal protection as specified in Section 8. Storage:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Do not pierce or burn, even after use.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Hazardous Ingredients OSHA ppm mg/m3 Naphtha (Petroleum), Hydrotreated Heavy* – – Petroleum Gases, Liquefied, Sweetened 1000 –
ACGIH TLV ppm mg/m3 – – 1000 –
AUSTRALIA ppm mg/m3 – – 1000 –
*Chesterton recommended limit: 171 ppm (1200 mg/m3).
A.W. Chesterton Company, 2010 All Rights Reserved.
Reg. US Patent and TM Office
Page 2 of 5
Product: 274 Industrial Degreaser (Aerosol) Date: 5 August 2010
MSDS No.: 207A-14
Respiratory Protection:
Not normally needed. If exposure limits are exceeded, use approved organic vapor respirator.
Ventilation:
Use only in well-ventilated areas. If exposure limits are exceeded, provide adequate ventilation. Vapors are heavier than air and will collect in low areas.
Protective Gloves:
Chemical resistant gloves (e.g. Viton*, neoprene, nitrile). *DuPont's ed trademark.
Eye Protection:
Safety glasses
Other:
Impervious clothing (e.g. Viton*, neoprene or nitrile) as necessary to prevent skin . *DuPont's ed trademark.
9. PHYSICAL AND CHEMICAL PROPERTIES low viscosity liquid Physical state clear Colour 188°C (370°F), product Initial boiling point only not determined Melting point 100% % Volatile (by volume) 61°C (142°F), product Flash point only Closed Cup Method not determined Viscosity 227°C (440°F), product Autoignition temp. only LEL 1.2; UEL 9.9 Explosion limits
Odour Vapour pressure @ 20C % Aromatics by weight
mild odor not applicable ≤ 0.01%, product only
pH Density Weight per volume
not applicable 0,77 kg/l 6.4 lbs/gal.
Coefficient (water/oil) Vapour density (air=1) Rate of evaporation (ether=1)
<1 >1 <1
Solubility in water Other
negligible none
10. STABILITY AND REACTIVITY Stable Stability: Hazardous Polymerization:
Will not occur.
Hazardous Decomposition Products:
Carbon Monoxide, aldehydes and other toxic fumes.
Conditions to Avoid:
Open flames, heat, sparks and red hot surfaces.
Materials to Avoid:
Reactive metals and strong oxidizers like liquid Chlorine and concentrated Oxygen.
11. TOXICOLOGICAL INFORMATION Inhalation, skin and eye . Personnel with pre-existing dermatitis may be Primary Route of Exposure Under aggravated by exposure. Normal Use: Acute Effects:
Direct eye may result in eye irritation. Inhalation of vapor concentrations in excess of 1000 ppm will cause eye and respiratory tract irritation, dizziness, headache and other central nervous system effects.
Chronic Effects:
Prolonged or repeated skin may defat the skin and cause skin irritation.
Other Information:
As per 29 CFR 1910.1200 (Hazard Communication), this product contains no carcinogens as listed in the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC) or the Occupational Safety and Health istration (OSHA).
A.W. Chesterton Company, 2010 All Rights Reserved.
Reg. US Patent and TM Office
Page 3 of 5
Product: 274 Industrial Degreaser (Aerosol) Date: 5 August 2010
MSDS No.: 207A-14
12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. The information given below is based on a knowledge of the components and the ecotoxicology of similar substances. Mobility:
Liquid. Insoluble in water. Floats on water. In determining environmental mobility, consider the product's physical and chemical properties (see Section 9). The hazardous ingredients will rapidly evaporate to the air if released into the water.
Degradability:
Naphtha (Petroleum), Hydrotreated Heavy: can degrade in air; may biodegrade. This substance is expected to be removed in a wastewater treatment facility.
Accumulation:
not determined
Ecotoxicity:
not determined
13. DISPOSAL CONSIDERATIONS Incinerate absorbed material with a properly licensed facility. Incinerate pressurized or sealed containers in an approved facility. Check local, state and national/federal regulations and comply with the most stringent requirement. This product is classified as a hazardous waste according to 91/689/EEC. EWC-code:
15 01 10
14. TRANSPORT INFORMATION UN1950, AEROSOLS, FLAMMABLE, CLASS 2.1, TDG: IMDG:
UN1950, AEROSOLS, CLASS 2.1, UN1950, EmS FD, S-U, ERG No 126 LIMITED QUANTITY
IATA/ICAO:
UN1950, AEROSOLS, FLAMMABLE, CLASS 2.1,
ADR/RID:
UN1950 AEROSOLS, 2, 5F, ADR
U.S. DOT : Shipping Name: 1 AEROSOLS, FLAMMABLE Hazard Class: 2.1 UN/NA #: UN1950 Packaging Group #: Not Applicable Emergency Response Guide Book No 126 1 NOTE: Shipped as Consumer Commodity ORM-D in packaging having a rated capacity gross weight of 66 lb. or less (49 CFR 173.306(h)).
15. REGULATORY INFORMATION F+ - Extremely flammable European Classification¹: R-Phrase(s):
R66
Repeated exposure may cause skin dryness or cracking. *
S-Phrase(s):
S23A S24 S51
Do not breathe spray. Avoid with skin. Use only in well-ventilated areas.
Name of the substances on the label:
none
Other information:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No Smoking.
Canadian Classification¹:
B5: Flammable aerosols; A: Compressed gases
Risk Phrase(s):
Flammable aerosol. Repeated exposure may cause skin dryness or cracking.
Precautionary and First Aid Measure(s):
Do not breathe spray. Avoid with skin. Use only in well-ventilated areas. If affected by vapor, move to fresh air. In case of with eyes, rinse with plenty of water and seek medical advice. Wash skin with soap and water.
Other Information:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No Smoking.
A.W. Chesterton Company, 2010 All Rights Reserved.
Reg. US Patent and TM Office
Page 4 of 5
Product: 274 Industrial Degreaser (Aerosol) Date: 5 August 2010
MSDS No.: 207A-14
16. OTHER INFORMATION US EPA SARA TITLE III 312 Hazards : 313 Chemicals : Immediate Fire Pressure Release
Hazardous Materials Identification System (HMIS) 4 = Severe Hazard 1 HEALTH 3 2 1 0 *
none TSCA: All chemical components are listed in the TSCA inventory.
JAPAN PRTR Class I Chemicals : none Risk phrases in section 3:
R12 R65 R66
= = = = =
Serious Hazard Moderate Hazard Slight Hazard Minimal Hazard See Section 8
FLAMMABILITY REACTIVITY Personal Protection
3 1 *
Class II Chemicals : none Extremely flammable. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking.
Changes to the MSDS in this revision:
Sections
*R65: not applicable according to criteria (aerosol). This information is based solely on data provided by suppliers of the materials used, not on the mixture itself. No warranty is expressed or implied regarding the suitability of the product for the ’s particular purpose. The must make their own determination as to suitability.
A.W. Chesterton Company, 2010 All Rights Reserved.
Reg. US Patent and TM Office
Page 5 of 5
274 Industrial Degreaser (Aerosol)
5 August 2010
Date of issue:
6 July 2007
207A-14
Not classified as hazardous according to criteria of Safe Work Australia. Company: A.W. CHESTERTON COMPANY 860 Salem Street Groveland, MA 01834-1507, USA Tel.: +1 978-469-6446 Fax: +1 978-469-6785 (Mon. - Fri. 8:30 - 5:00 PM EST) E-mail (MSDS questions): [email protected] MSDS requests: www.chesterton.com
Supplier:
For Chemical Emergency: 24 hours per day, 7 days per week Call Infotrac: 1-800-535-5053 Outside N. America: +1 352-323-3500 (collect) Use:
Petroleum base cleaner. Dissolves grease, oil, tar and other similar water insoluble soils generally encountered in the industrial and marine environments.
2. HAZARDS IDENTIFICATION Highly flammable. Contents under pressure. Repeated exposure may cause skin dryness or cracking. As with any organic solvent based product, care should be taken to avoid excessive inhalation of vapors. This is especially important in enclosed areas or areas with poor ventilation. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Ingredients¹ % Wt. CAS No. Naphtha (Petroleum), Hydrotreated Heavy* 85-95 64742-48-9 Petroleum Gases, Liquefied, Sweetened** 10-20 68476-86-8
EC No. 265-150-3 270-705-8
Symbol Xn F+
R-phrases 65-66 12
See section 15 for text of risk phrases on the label and section 16 for others. *Contains less than 0.1 % w/w Benzene. **Contains less than 0.1 % w/w 1,3-Butadiene.
© A.W. Chesterton Company, 2010 All Rights Reserved. ® Reg. US Patent and TM Office
¹Classified according to:
* 29 CFR 1910.1200, 1915, 1916, 1917 * Mass. Right-to-Know Law (ch. 40, M.G.L..O. 111F) * California Proposition 65 * Controlled Products Regulations * 67/548/EEC, 1272/2008/EC (ATP01) 99/45/EC and 75/324/EEC * Worksafe Australia [NOHSC: 1008 (2004)]
Page 1 of 5
Product: 274 Industrial Degreaser (Aerosol) Date: 5 August 2010
MSDS No.: 207A-14
4. FIRST AID MEASURES Remove to fresh air. If not breathing, ister artificial respiration. physician immediately. Inhalation: Skin :
Wash skin with soap and water. physician if irritation persists.
Eye :
Flush eyes for at least 15 minutes with large amounts of water. physician if irritation persists.
Ingestion:
Do not induce vomiting. physician immediately.
Advice to Physician:
Treat symptoms.
5. FIRE-FIGHTING MEASURES Extinguishing Methods:
Carbon Dioxide, dry chemical, foam or water spray
Unusual Fire and Explosion Hazards:
Pressurized containers, when heated, are a potential explosive hazard.
Special Fire Fighting Measures:
Cool exposed containers with water. Recommend Firefighters wear self-contained breathing apparatus.
Flammability Classification:
NFPA: Storage Level III; 16CFR 1500.3 Extremely flammable aerosol
HAZCHEM Emergency Action Code: 2 Y 6. ACCIDENTAL RELEASE MEASURES Utilize exposure controls and personal protection as specified in Section 8. Personal Precautions: Environmental Precautions:
Keep out of sewers, streams and waterways.
Methods of Clean Up:
Evacuate area. Provide adequate ventilation. Contain spill to a small area. Keep away from sources of ignition - No smoking. If removal of ignition sources is not possible, then flush material away with water. Pick up with absorbent material (sand, sawdust, clay, etc.) and place in a suitable container for disposal. Refer to section 13 for disposal advice.
7. HANDLING AND STORAGE Handling: Shake well before using. Keep away from sources of ignition - No smoking. After handling, wash before eating, drinking or smoking. Vapors are heavier than air and will collect in low areas. Vapor accumulations could flash and/or explode if ignited. Utilize exposure controls and personal protection as specified in Section 8. Storage:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Do not pierce or burn, even after use.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Hazardous Ingredients OSHA ppm mg/m3 Naphtha (Petroleum), Hydrotreated Heavy* – – Petroleum Gases, Liquefied, Sweetened 1000 –
ACGIH TLV ppm mg/m3 – – 1000 –
AUSTRALIA ppm mg/m3 – – 1000 –
*Chesterton recommended limit: 171 ppm (1200 mg/m3).
A.W. Chesterton Company, 2010 All Rights Reserved.
Reg. US Patent and TM Office
Page 2 of 5
Product: 274 Industrial Degreaser (Aerosol) Date: 5 August 2010
MSDS No.: 207A-14
Respiratory Protection:
Not normally needed. If exposure limits are exceeded, use approved organic vapor respirator.
Ventilation:
Use only in well-ventilated areas. If exposure limits are exceeded, provide adequate ventilation. Vapors are heavier than air and will collect in low areas.
Protective Gloves:
Chemical resistant gloves (e.g. Viton*, neoprene, nitrile). *DuPont's ed trademark.
Eye Protection:
Safety glasses
Other:
Impervious clothing (e.g. Viton*, neoprene or nitrile) as necessary to prevent skin . *DuPont's ed trademark.
9. PHYSICAL AND CHEMICAL PROPERTIES low viscosity liquid Physical state clear Colour 188°C (370°F), product Initial boiling point only not determined Melting point 100% % Volatile (by volume) 61°C (142°F), product Flash point only Closed Cup Method not determined Viscosity 227°C (440°F), product Autoignition temp. only LEL 1.2; UEL 9.9 Explosion limits
Odour Vapour pressure @ 20C % Aromatics by weight
mild odor not applicable ≤ 0.01%, product only
pH Density Weight per volume
not applicable 0,77 kg/l 6.4 lbs/gal.
Coefficient (water/oil) Vapour density (air=1) Rate of evaporation (ether=1)
<1 >1 <1
Solubility in water Other
negligible none
10. STABILITY AND REACTIVITY Stable Stability: Hazardous Polymerization:
Will not occur.
Hazardous Decomposition Products:
Carbon Monoxide, aldehydes and other toxic fumes.
Conditions to Avoid:
Open flames, heat, sparks and red hot surfaces.
Materials to Avoid:
Reactive metals and strong oxidizers like liquid Chlorine and concentrated Oxygen.
11. TOXICOLOGICAL INFORMATION Inhalation, skin and eye . Personnel with pre-existing dermatitis may be Primary Route of Exposure Under aggravated by exposure. Normal Use: Acute Effects:
Direct eye may result in eye irritation. Inhalation of vapor concentrations in excess of 1000 ppm will cause eye and respiratory tract irritation, dizziness, headache and other central nervous system effects.
Chronic Effects:
Prolonged or repeated skin may defat the skin and cause skin irritation.
Other Information:
As per 29 CFR 1910.1200 (Hazard Communication), this product contains no carcinogens as listed in the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC) or the Occupational Safety and Health istration (OSHA).
A.W. Chesterton Company, 2010 All Rights Reserved.
Reg. US Patent and TM Office
Page 3 of 5
Product: 274 Industrial Degreaser (Aerosol) Date: 5 August 2010
MSDS No.: 207A-14
12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. The information given below is based on a knowledge of the components and the ecotoxicology of similar substances. Mobility:
Liquid. Insoluble in water. Floats on water. In determining environmental mobility, consider the product's physical and chemical properties (see Section 9). The hazardous ingredients will rapidly evaporate to the air if released into the water.
Degradability:
Naphtha (Petroleum), Hydrotreated Heavy: can degrade in air; may biodegrade. This substance is expected to be removed in a wastewater treatment facility.
Accumulation:
not determined
Ecotoxicity:
not determined
13. DISPOSAL CONSIDERATIONS Incinerate absorbed material with a properly licensed facility. Incinerate pressurized or sealed containers in an approved facility. Check local, state and national/federal regulations and comply with the most stringent requirement. This product is classified as a hazardous waste according to 91/689/EEC. EWC-code:
15 01 10
14. TRANSPORT INFORMATION UN1950, AEROSOLS, FLAMMABLE, CLASS 2.1, TDG: IMDG:
UN1950, AEROSOLS, CLASS 2.1, UN1950, EmS FD, S-U, ERG No 126 LIMITED QUANTITY
IATA/ICAO:
UN1950, AEROSOLS, FLAMMABLE, CLASS 2.1,
ADR/RID:
UN1950 AEROSOLS, 2, 5F, ADR
U.S. DOT : Shipping Name: 1 AEROSOLS, FLAMMABLE Hazard Class: 2.1 UN/NA #: UN1950 Packaging Group #: Not Applicable Emergency Response Guide Book No 126 1 NOTE: Shipped as Consumer Commodity ORM-D in packaging having a rated capacity gross weight of 66 lb. or less (49 CFR 173.306(h)).
15. REGULATORY INFORMATION F+ - Extremely flammable European Classification¹: R-Phrase(s):
R66
Repeated exposure may cause skin dryness or cracking. *
S-Phrase(s):
S23A S24 S51
Do not breathe spray. Avoid with skin. Use only in well-ventilated areas.
Name of the substances on the label:
none
Other information:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No Smoking.
Canadian Classification¹:
B5: Flammable aerosols; A: Compressed gases
Risk Phrase(s):
Flammable aerosol. Repeated exposure may cause skin dryness or cracking.
Precautionary and First Aid Measure(s):
Do not breathe spray. Avoid with skin. Use only in well-ventilated areas. If affected by vapor, move to fresh air. In case of with eyes, rinse with plenty of water and seek medical advice. Wash skin with soap and water.
Other Information:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No Smoking.
A.W. Chesterton Company, 2010 All Rights Reserved.
Reg. US Patent and TM Office
Page 4 of 5
Product: 274 Industrial Degreaser (Aerosol) Date: 5 August 2010
MSDS No.: 207A-14
16. OTHER INFORMATION US EPA SARA TITLE III 312 Hazards : 313 Chemicals : Immediate Fire Pressure Release
Hazardous Materials Identification System (HMIS) 4 = Severe Hazard 1 HEALTH 3 2 1 0 *
none TSCA: All chemical components are listed in the TSCA inventory.
JAPAN PRTR Class I Chemicals : none Risk phrases in section 3:
R12 R65 R66
= = = = =
Serious Hazard Moderate Hazard Slight Hazard Minimal Hazard See Section 8
FLAMMABILITY REACTIVITY Personal Protection
3 1 *
Class II Chemicals : none Extremely flammable. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking.
Changes to the MSDS in this revision:
Sections
*R65: not applicable according to criteria (aerosol). This information is based solely on data provided by suppliers of the materials used, not on the mixture itself. No warranty is expressed or implied regarding the suitability of the product for the ’s particular purpose. The must make their own determination as to suitability.
A.W. Chesterton Company, 2010 All Rights Reserved.
Reg. US Patent and TM Office
Page 5 of 5
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