Msds Alodine 1000 c2k1g

Material Safety Data Sheet

Henkel Revision Number: 004.1

Product name: Product type:

Issue date: 09/18/2009

ALODINE 1000 RTU Coating

IDH number:

Region: United States i n f o r m a t i o n : Teiephone: 248.583.9300 For Chemical Emergency Call CHEMTREC at 800.424.9300 internet: www.henkelna com

Company address: Henkel Corporation 32100 Stephenson Highway Madison Heights. Mi 48071

Physical state: Color: Odor:

598168

Liquid Orange Odorless

WARNING:

Relevant routes of e x p o s u r e :

EMERGENCY OVERVIEW HMIS: HEALTH: FLAMMABILITY: PHYSICAL HAZARD: Personal Protection:

'2 0 0 See MSDS Section 8

CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. POSSIBLE CANCER HAZARD. Skin, Inhalation, Eyes

Potential Health Effects Inhalation: Skin :

Eye : Ingestion: Existing conditions aggravated by exposure:

Prolonged or repeated breathing may cause ulceration of nasal membranes. Product contains chromium, which may cause an allergic skin sensitization reaction. Liquid or vapor can cause fluoride-type irritation or burns which may not be immediately painful or visible. Prolonged or widespread may result in the absorption of potentially hannful amounts of material. This product may be severely irritating to the eyes. Acute ingestion may result in mild gastrointestinal distress. Eye, skin and respiratory disorders.

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910 1200). See Section 11 for additional toxicological Information.

Hazardous c o m p o n e n t s

CAS NUMBER

%

Chromic a d d Dipotassium tiexafiuorozirconate

7738-94-5 16923-95-8

0.1-1 0.1-1

fURE! Inhalation:

m:^^_s2

If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist.

IDH number: 598168

Product name: ALODINE 1000 RTU Page 1 of 5

Skln :

Remove contaminated clothing and footwear. For skin , flush with large amounts ofwater. Seek immediate medical attention. Discard any shoes or clothing items that cannot be decontaminated.

Eye :

In case of with the eyes, rinse immediately wilh plenty of water for 15 minutes, and seek immediate medical attention.

Ingestion:

Get immediate medical attention. Do nol induce vomiting. Give one lo two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions.

Notes to p h y s i c i a n :

Treat symptomatically and iveiy.

5. FIRE FIGHTING M E A ^ i f ^ Flash point:

Not applicable

A u t o i g n i t i o n temperature:

Not applicable

Flammable/Explosive limits • lower:

Not applicable

Flammable/Explosive limits - upper:

Not applicable

Extinguishing media:

Use media appropriate for surrounding material.

Special firefighting procedures:

Wear full protective clothing. Wear self-contained breathing apparatus.

Unusual fire or explosion hazards:

This product is an aqueous mixture which will not burn.

Hazardous c o m b u s t i o n p r o d u c t s :

Irritating and toxic gases or fumes may be released during a fire.

Use personal protection recommended In Section 8, isolate the hazard area and deny entry t o unnecessary and unprotected personnel. Environmental precautions:

Prevent further leakage or spillage if safe to do so. Wear appropriate protective equipment and clothing during clean-up.

Clean-up methods:

Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, Stale and local governmental regulations.

Tlf^W^.

L\HQ AND ST01

Handling:

Avoid with eyes, skin and clothing. Wash thoroughly afler handling.

Storage:

For safe storage, store at or above 40 ' F (4.4 °C) Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials.

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

Employers s h o u l d complete an assessment of all workplaces to determine the need for, a n d selection of, proper exposure controls and protective equipment for each task performed.

IDH number: 598168

Product name: ALODINE 1000 RTU Page 2 of 5

Hazardous components

ACGIH TLV

Chromic acid

0,05 mg/m3 TWA (as Cr)

Dipotassium hexafluorozirconate

5 mg/m3 TWA (as Zr) 10mg/m3STEL (as Zr) 2.5 mg/m3 TWA (asF)

OSHA PEL 0.1 mg/m3 Ceiling 0.005 mg/m3 TWA (SKIN) 0.0025 mg/m3 OSHA ACT 29 CFR 1910.1026 5 mg/m3 TWA (as Zr) 2.5 mg/m3 TWA Dust. 2.5 mg/m3 TWA (asF)

AIHA WEEL

OTHER

None

None

None

None

Engineering c o n t r o l s :

Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product.

Respiratory p r o t e c t i o n :

If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided.

Eye/face protection:

Wear chemical goggles; face shield (if splashing is possible).

Skin protection:

Chemical resistant, impermeable gloves. Use of impervious apron and boots are recommended.

AND CHEMICAL physical state: Color: Odor; Odor t h r e s h o l d : pH: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits • lower: Flammable/Explosive limits • upper: A u t o i g n i t i o n temperature: Evaporation rate; Solubility in water: Partition coefficient (n-octanol/water): VOC content:

Liquid Orange Odoriess Not available 1.7-2.2 Not detemiined >100°C(>212T) 3 0 ° F ( - 1 . 1 °C) 1.00-1.02 Not determined Not applicable Not applicable Not applicable Not applicable Not determined Complete Not determined Not applicable

Stability

Stable at normal conditions.

Hazardous reactions:

Will not occur.

Hazardous d e c o m p o s i t i o n p r o d u c t s :

Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons.

Incompatible materials:

Avoid with organic materials, oils, greases, and any oxidizable materials. Keep away from alkalis.

Conditions to a v o i d :

Do not allow chemical to dry in the presence of organic materials.

Product name: ALODINE 1000 RTU

IDH number: 598168 Page 3 of 5

OSHA Carcinogen Hazardous c o m p o n e n t s

NTP Carcinogen

IARC Carcinogen

Known carcinoqen. No

Group 1 No

(Specifically Regulated) Chromic acid Dipotassium he^fafluorozirconate Hazardous c o m p o n e n t s

Yes No

Health Effects/Target Organs Allergen, Blood, Carcinogen, Central nervous system. Corrosive. Developmental, Eyes, Gastrointestinal, Irritant. Kidney, Liver, Mutagen, Reproductive, Respiratory Allergen, Blood, Cardiac, Central nervous system. Corrosive, Gastrointestinal tract. Irritant, Kidney, Lung, Metabolic, Muscle, Teeth, Less weight gain and food intake.

Chromic acid

Dipotassium he^^afluorozirconate

Ecological i n f o r m a t i o n :

Not available

13. fPISROSAL CONSIDEfWfU Information provided is for unused p r o d u c t only. Recommended method of d i s p o s a l :

Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number:

This product contains chromium which is a hazardous waste (D007). This producL if discarded, may be characterized as a RCRA corrosive waste, D002.

The shipping classification in this section are for bulk packaging only. Shipping classification may be different for non-bulk packaging as exceptions may apply. Refer to shipping documents for package specific transportation classification. U.S. Department of Transportation Ground (49 CFR> Proper s h i p p i n g name: Environmentally hazardous substances, liquid, n.o.s. Hazard class or d i v i s i o n : 9 Identification number: UN 3062 Packing g r o u p : III DOT Reportable quantity: Chromic acid International Air Transportation nCAO/IATAl Proper s h i p p i n g name: Environmentally hazardous substance, liquid, n.o.s. Hazard class or d i v i s i o n : 9 Identification number: UN 3082 Packing g r o u p : 111 Water Transportation (IMO/IMDGl Proper s h i p p i n g name: Hazard class or d i v i s i o n : Identification number: Packing g r o u p :

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

9 UN 3082 III

United States Regulatorv Information TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification:

All componenls are listed or are exempt from listing on the Toxic Substances Control Act Inventory. Chromic acid (CAS# 7738-94-5).

CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312:

None above reporting de minimus Immediate Health, Delayed Health

IDH number: 598168

Producl name: ALODINE 1000 RTU Page 4 of 5

CERCLA/SARA 313:

CERCLA Reportable quantity: California Proposition 65:

This product contains the following toxic chemicals subject to the reporting requirements of section 313 ofthe Emergency Planning and Community Right-To-Know Act of 1986(40 CFR 372). Chromic acid (CAS# 7738-94-5). Chromic acid (CAS# 7738-94-5) 10 lbs. (4.54 kg) This product contains a chemical known in the Stata of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

Canada ReQulatorv Information CEPA D S U N D S L Status: WHMIS hazard class:

All components are listed on or are exempt from listing on the Canadian Domestic Substances List. D.2.A, D.2.B. E

This material safety data sheet contains changes f r o m the previous version in s e c t i o n s : New Material Safety Data Sheet format. Prepared b y : John DiCerbo. Regulalory Affairs Specialist DISCLAIMER: The data contained herein are f u r n i s h e d for information only a n d are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over w h o s e methods Henkel Corporation has no c o n t r o l . It Is the 's responsibility t o determine the suitability of Henkel's products or any p r o d u c t i o n methods mentioned herein for a particular purpose, and to adopt s u c h precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's p r o d u c t s . In light of the f o r e g o i n g , Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability a n d fitness for a particular purpose, arising f r o m sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability f o r consequential or incidental damages of any k i n d . Including lost profits.

IDH number: 598168

Productname ALODINE 1000 RTU Page 5 of 5